natural kaolin supported sulfuric acid as an efficient catalyst for the preparation of 1, 1-diacetates under solvent-free conditions
نویسندگان
چکیده
a facile and efficient method for the preparation of 1,1-diacetates of aldehydes is improved. the acidified kaolin with sulfuric acid (2 % w/w) catalyzed 1,1-diacetates formation from aldehydes in solvent-free conditions. both aromatic and aliphatic aldehydes gave high yields (85-95 %) of the corresponding 1, 1-diacetates. advantages of this method are the use of inexpensive and selective catalyst, with high yields in simple operation, and short reaction time under solvent-free conditions.
منابع مشابه
Natural Kaolin supported sulfuric acid as an efficient catalyst for the preparation of 1, 1-diacetates under solvent-free conditions
A facile and efficient method for the preparation of 1,1-diacetates of aldehydes is improved. The acidified kaolin with sulfuric acid (2 % w/w) catalyzed 1,1-diacetates formation from aldehydes in solvent-free conditions. Both aromatic and aliphatic aldehydes gave high yields (85-95 %) of the corresponding 1, 1-diacetates. Advantages of this method are the use of inexpensive and selective catal...
متن کاملNatural Kaolin supported sulfuric acid as an efficient catalyst for the preparation of 1, 1-diacetates under solvent-free conditions
A facile and efficient method for the preparation of 1,1-diacetates of aldehydes is improved. The acidified kaolin with sulfuric acid (2 % w/w) catalyzed 1,1-diacetates formation from aldehydes in solvent-free conditions. Both aromatic and aliphatic aldehydes gave high yields (85-95 %) of the corresponding 1, 1-diacetates. Advantages of this method are the use of inexpensive and selective catal...
متن کاملp2o5 / sio2 as catalyst for the preparation of 1, 1-diacetates under solvent-free conditions
a facile and efficient method for the preparation of 1, 1-diacetates of aldehydes is improved.p2o5/sio2 catalyzed 1, 1-diacetates formation from aldehydes in dry media. advantages of this methodare the use of an inexpensive and selective catalyst with high yields in simple operation and shortreaction time under solvent-free conditions.
متن کامل4-Sulfobenzoic Acid as an Efficient Catalyst for the Preparation of 3,4-dihydropyrimidin-2-(1H)-ones Under Solvent-free Conditions
In this research, one-pot three-component synthesis of 3,4-dihydropyrimidin-2-(1H)-ones havebeen developed using Biginelli reaction from the interaction between ethyl/methyl acetoacetate,aromatic aldehydes, and urea/thiourea in the presence of 4-sulfobenzoic acid as a new, effective,inexpensive, and available bronsted acid. Avoidance of toxic and dangerous solvents, easy isola...
متن کاملDipyridine cobalt chloride as an efficient and chemoselective catalyst for the synthesis of 1,1-diacetates under solvent-free conditions
1,1-Diacetates(acylals) were prepared by direct condensation of various aldehydes with acetic anhydride using dipyridine cobalt chloride (CoPy2Cl2) as an efficient and green catalyst under solvent-free conditions at room temperature. The important features of this catalyst method are that the catalyst is solid, stable at high temperatures, soluble in water, stable in air, immiscible in common o...
متن کامل4-dodecylbenzenesulfonic acid (dbsa): an efficient, eco-friendly and chemoselective catalyst for the synthesis of 1, 1- diacetates under solvent-free conditions at room temperature
4-dodecylbenzenesulfonic acid (dbsa) has been shown to be an efficient, mild, green, stable and chemoselective brønsted acid catalyst for the synthesis of 1, 1-diacetates (acylals) of aldehydes under solvent-free conditions. the mild condition, eco-friendly, excellent yields, short reaction times and using an easily available, inexpensive and reusable catalyst are important features of this met...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
iranian journal of catalysisناشر: islamic azad university, shahreza branch
ISSN 2252-0236
دوره 1
شماره 1 2011
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023